By R. Mildon (auth.), W. F. Raymond, P. Larvor (eds.)
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It is possible with an amount of fructose of 42%, to separate it from the glucose by continuous liquid chromatography. The concentration of D-fructose obtained in the syrups can reach 95% to 97% from which it is easy to obtain D-fructose by crystallisation on a yearly production basis which surpasses 20 000 tons (Figure 8). At this stage, the development (to be encouraged) of hydroxymethylfurfural chemistry and its derivatives on an industrial scale offers very 53 ACIDIC DEGRADATION/DEHYDRATION D-GLUCOSE ISOMERISATION 3n C H,CH,COOH D-FRUCTOSE , CH o LEVULINIC ACID R = R' = CH 20H, CHO, CH=CH 2 , C~-5H2' COOH, COOR, CH 2CN, WITH o R' = -CHO, R = CN, CONH 2 , COOH, COOR Fig.
2 1. 3 i 33 - 25 "";isopropyl nitrate 01 DIESEL ENGINE CR 17 ! RATED SPEED NO LOAD . n-butyl nitrate 20 w '":> .... isoamyl )( >: o « '">w o '">: 15 0.. z o 10 I nitrate(OI~nd or ISome,,' • 'V-triethyl ammonium nitrate 6, .. somersl · 2-ethoxyethyl nitrale I( 2-ethylhexyl nitrate . 2- octyl nitrate ~ n-octyl nitrate \ n-heptyl ni trat e cyclohexyl nitrate .... ~ o w '"::> CY diethylene glycol dinitrateO 5 w t riethylene glycol dinitrate9 '" o 100 1SO 200 MOLECULAR WE I GHT 250 (g/mo1e) Fig. 27.
0. 790. 310. 3 78 sa Fig. 9. 8 Spec. Gravity g/cm3 bar RVP 28 ... 65 30 ... 1 CH 30H as 88 C7 Hls Gasoline Ml00 (premium) (Winter) MON 'I, 'I, Unit RON CsH12 ~O Fig. 8. ~ 00 0 0 00 :';:\ 40 60 ~ 50 70 '- 00 80 90 100 Fig. 7. 92 Vegetable Oil Cetane Number Filtration Limit Kin. 750 g/ml % vol. Components ______ ______ -+__ ~ 15 10 ~ 20 Fig. 10. Oxygen Content of Oxygenated Gasoline COMPONENT % SOlUB I LI SER IGNITION IMPR. 5 Fig. 11. Alcohol/Diesel Blend Fuel Data 60 f=:=::-- k r----=::: ~ t---.
Alternative Uses for Agricultural Surpluses by R. Mildon (auth.), W. F. Raymond, P. Larvor (eds.)